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Pre-Workout supps contain additive things that support extended endurance, that's all really. "High energy snack" is one that contains a mix of simple and complex carbs, that's it really. Coffee gets you your caffeine for that "lets go" feeling.
Many PW supps contain L-Citruline which is one of the core NO boosters. Its really those NO boosters that preworkouts provide that isn't easily found in food.
Really all supplements are are shortcuts. Good or bad, personal and wallet choice really. Guaranteed shortcuts though they are not.
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